Is it possible to metasploit in Kali without the payload exe?

[Xnehaxixh]

Is it possible to exploit a pc by Kali Linux without running the exe (file produced by msfvenom) in the victim's pc using metapreter?

[digip]

I think you need to read up a bit more on exploitation in general, and what it is you're trying to achieve. There are plenty of payloads that don't use windows executables, but it most cases, getting a user to do something like click a link or run a program is generally the easier path. Plenty of exploits for systems that require no user intervention to make attacks happen though. Again, read up on exploits and also MSF in general.